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Sep 17, 2010

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All This Burning Cars

Fire

Fire is the rapid oxidation of a material in the chemical process of combustion, releasing heat, light, and various reaction products. Slower oxidative processes like rusting or digestion are not included by this definition.

The flame is the visible portion of the fire and consists of glowing hot gases. If hot enough, the gases may become ionized to produce plasma. Depending on the substances alight, and any impurities outside, the color of the flame and the fire’s intensity might vary.

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Fire in its most common form can result in conflagration, which has the potential to cause physical damage through burning. Fire is an important process that affects ecological systems across the globe. The positive effects of fire include stimulating growth and maintaining various ecological systems. Fire has been used by humans for cooking, generating heat, signaling, and propulsion purposes. The negative effects of fire include decreased water purity, increased soil erosion, an increase in atmospheric pollutants and an increased hazard to human life.

Fires start when a flammable and/or a combustible material, in combination with a sufficient quantity of an oxidizer such as oxygen gas or another oxygen-rich compound (though non-oxygen oxidizers exist that can replace oxygen), is exposed to a source of heat or ambient temperature above the flash point for the fuel/oxidizer mix, and is able to sustain a rate of rapid oxidation that produces a chain reaction. This is commonly called the fire tetrahedron. Fire cannot exist without all of these elements in place and in the right proportions. For example, a flammable liquid will start burning only if the fuel and oxygen are in the right proportions. Some fuel-oxygen mixes may require a catalyst, a substance that is not directly involved in any chemical reaction during combustion, but which enables the reactants to combust more readily.

Once ignited, a chain reaction must take place whereby fires can sustain their own heat by the further release of heat energy in the process of combustion and may propagate, provided there is a continuous supply of an oxidizer and fuel.

Fire can be extinguished by removing any one of the elements of the fire tetrahedron. Consider a natural gas flame, such as from a stovetop burner.

Flame
A flame is a mixture of reacting gases and solids emitting visible and infrared light, the frequency spectrum of which depends on the chemical composition of the burning material and intermediate reaction products. In many cases, such as the burning of organic matter, for example wood, or the incomplete combustion of gas, incandescent solid particles called soot produce the familiar red-orange glow of ‘fire’. This light has a continuous spectrum. Complete combustion of gas has a dim blue color due to the emission of single-wavelength radiation from various electron transitions in the excited molecules formed in the flame. Usually oxygen is involved, but hydrogen burning in chlorine also produces a flame, producing hydrogen chloride (HCl). Other possible combinations producing flames, amongst many, are fluorine and hydrogen, and hydrazine and nitrogen tetroxide.

The glow of a flame is complex. Black-body radiation is emitted from soot, gas, and fuel particles, though the soot particles are too small to behave like perfect blackbodies. There is also photon emission by de-excited atoms and molecules in the gases. Much of the radiation is emitted in the visible and infrared bands. The color depends on temperature for the black-body radiation, and on chemical makeup for the emission spectra. The dominant color in a flame changes with temperature. The photo of the forest fire is an excellent example of this variation. Near the ground, where most burning is occurring, the fire is white, the hottest color possible for organic material in general, or yellow. Above the yellow region, the color changes to orange, which is cooler, then red, which is cooler still. Above the red region, combustion no longer occurs, and the uncombusted carbon particles are visible as black smoke.

The National Aeronautics and Space Administration (NASA) of the United States has recently found that gravity also plays a role in flame formation. Modifying the gravity causes different flame types. The common distribution of a flame under normal gravity conditions depends on convection, as soot tends to rise to the top of a general flame, as in a candle in normal gravity conditions, making it yellow. In micro gravity or zero gravity, such as an environment in outer space, convection no longer occurs, and the flame becomes spherical, with a tendency to become more blue and more efficient (although it may go out if not moved steadily, as the CO2 from combustion does not disperse as readily in micro gravity, and tends to smother the flame). There are several possible explanations for this difference, of which the most likely is that the temperature is sufficiently evenly distributed that soot is not formed and complete combustion occurs. Experiments by NASA reveal that diffusion flames in micro gravity allow more soot to be completely oxidized after they are produced than diffusion flames on Earth, because of a series of mechanisms that behave differently in micro gravity when compared to normal gravity conditions. These discoveries have potential applications in applied science and industry, especially concerning fuel efficiency.
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Automobile
An automobile, motor car or car is a wheeled motor vehicle used for transporting passengers, which also carries its own engine or motor. Most definitions of the term specify that automobiles are designed to run primarily on roads, to have seating for one to eight people, to typically have four wheels, and to be constructed principally for the transport of people rather than goods. However, the term automobile is far from precise, because there are many types of vehicles that do similar tasks.

There are approximately 600 million passenger cars worldwide (roughly one car per eleven people). Around the world, there were about 806 million cars and light trucks on the road in 2007; they burn over 1 billion m³ (260 billion US gallons) of petrol/gasoline and diesel fuel yearly. The numbers are increasing rapidly, especially in China and India

Etymology
The word automobile comes, via the French automobile, from the Ancient Greek word αὐτός (autós, “self”) and the Latin mobilis (“movable”); meaning a vehicle that moves itself, rather than being pulled or pushed by a separate animal or another vehicle. The alternative name car is believed to originate from the Latin word carrus or carrum (“wheeled vehicle”), or the Middle English word carre (“cart”) (from Old North French), or from the Gaulish word karros (a Gallic Chariot).
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